Agent and method for the temporary deformation of keratin fibres

ABSTRACT

Cosmetic preparations based on hydrophobically modified (meth)acrylic acid copolymers and hydrophobically modified polysaccharides are described, together with related methods of use thereof for the temporary shaping of keratin-containing fibers, in particular human hair.

FIELD OF THE INVENTION

The present invention generally relates to the use of cosmetic agents for the temporary shaping of keratinic fibers, in particular human hair. The invention also provides specific agents for the temporary shaping of keratinic fibers.

BACKGROUND OF THE INVENTION

Styling agents for the shaping of keratin-containing fibers have long been known and are used in various embodiments to construct, refresh and set hairstyles which for many hair types can only be achieved by the use of active fixing agents. Both hair treatment agents serving to permanently shape the hair and those used for its temporary shaping have an important role to play here.

Agents for temporary shaping are available in various presentation forms, wherein among the propellant-free agents hair waxes and hair gels in particular are widespread. From a consumer perspective these agents differ from one another in particular also in terms of the product feel. The feel of a hair cosmetic is generally not the chance result of a combination of specific active agents; rather, along with other sensory properties such as appearance and odor, it is an essential means of supporting the product or brand proposition and is thus an important factor in the commercial success of the product.

The problem of the present patent application was therefore to provide cosmetic agents for the temporary shaping of keratinic fibers, having a novel feel and good cosmetic properties. In particular, the feel of the cosmetic agents should differ from the gels and waxes hitherto available on the market.

It was determined that these problems can be solved by a combination of hydrophobically modified (meth)acrylic acid copolymers and hydrophobically modified polysaccharides. Hair cosmetics agents based on this combination of active agents are characterized not only by a unique feel but also by good fixing properties, for example a high degree of hold combined with low stickiness, high flexibility and good moisture resistance—in particular resistance to perspiration and water. The combination of hydrophobically modified (meth)acrylic acid copolymers and hydrophobically modified polysaccharides is also suitable for producing compositions having a stable viscosity.

Cosmetic or dermatological light stabilizing preparations, which in addition to further ingredients contain an acrylates/C10-30 alkyl acrylate crosspolymer and an aluminum starch octenylsuccinate, are described in the German laid-open patent application DE 10 2010 063 842 A1 (Beiersdorf).

Furthermore, other desirable features and characteristics of the present invention will become apparent from the subsequent detailed description of the invention and the appended claims, taken in conjunction with the accompanying drawings and this background of the invention.

BRIEF SUMMARY OF THE INVENTION

Use of a cosmetic composition, containing at least one hydrophobically modified (meth)acrylic acid copolymer and at least one hydrophobically modified polysaccharide for the temporary shaping of keratin-containing fibers, in particular human hair.

A cosmetic composition, containing at least one hydrophobically modified (meth)acrylic acid copolymer, at least one hydrophobically modified polysaccharide, and at least one wax.

DETAILED DESCRIPTION OF THE INVENTION

The following detailed description of the invention is merely exemplary in nature and is not intended to limit the invention or the application and uses of the invention. Furthermore, there is no intention to be bound by any theory presented in the preceding background of the invention or the following detailed description of the invention.

The present application firstly provides the use of a cosmetic composition, containing

a) at least one hydrophobically modified (meth)acrylic acid copolymer;

b) at least one hydrophobically modified polysaccharide;

for the temporary shaping of keratin-containing fibers, in particular human hair.

The agents used according to the invention are characterized by a rubber-like consistency. This consistency makes the agents easy to dispense and apply.

The use according to the invention is preferably achieved in that the keratinic fibers are treated with one of the cosmetic compositions described above and temporarily fixed in their shape. The treatment of the keratinic fibers with the cosmetic composition preferably takes place by applying the cosmetic composition to the fingers or to the palms of the hand and then shaping the keratinic fibers with the fingers or palms, as a result of which at least some of the cosmetic composition is transferred from the fingers or the palms to the keratinic fibers.

The use of a cosmetic composition containing

a) at least one hydrophobically modified (meth)acrylic acid copolymer;

b) at least one hydrophobically modified polysaccharide;

for the temporary shaping and remodeling of keratin-containing fibers, in particular human hair, is particularly preferred.

A first essential constituent of cosmetic compositions used according to the invention is the hydrophobically modified (meth)acrylic acid copolymer a). The proportion by weight of the copolymer a) in the total weight of the cosmetic composition is preferably 0.05 to 5.0 wt. %, particularly preferably 0.1 to 4.0 wt. % and in particular 0.2 to 2.0 wt. %. Preferred copolymers a) have a thickening effect.

Copolymers which are derived from

-   -   at least one monomer (A1) from the group of unsaturated         carboxylic acids and unsaturated carboxylic acid esters, and     -   at least one monomer (A2) from the group of unsaturated         hydrophobically modified monomers are preferably used as         hydrophobically modified (meth)acrylic acid copolymers a).

Preferred copolymers A are based on at least one monomer (A1) from the group of acrylic acid, methacrylic acid, C₁-C₆ alkyl acrylic acid esters, C₁-C₆ alkyl methacrylic acid esters. The acrylic acid esters and methacrylic acid esters are preferably esters of the individual acids with non-tertiary alkyl alcohols having alkyl residues of 1 to 12 carbon atoms, in particular 2 to 4 carbon atoms. Suitable monomers which can be mentioned are for example ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, n-butyl acrylate, n-butyl methacrylate, isobutyl acrylate, 2-methylbutyl acrylate, 2-ethylhexyl acrylate, n-octyl acrylate, isooctyl acrylate, isooctyl methacrylate, isononyl acrylate and isodecyl acrylate.

The group of hydrophobically modified monomers (A2) refers to monomers having a hydrophobic substructure. Preferred monomers (A2) for their part are derived from the following two structural units:

-   -   an unsaturated acid, preferably acrylic acid, methacrylic acid         or itaconic acid;     -   a C₈₋₄₀ alkyl chain, preferably a C₁₀₋₃₀ alkyl chain.

These two substructures can optionally be supplemented by a third structural unit from the group of polyoxyalkylene groups, preferably polyethylene glycol groups, polypropylene glycol groups or polyethylene glycol/polypropylene glycol groups.

C₁₀₋₃₀ alkyl acrylates, C₁₀₋₃₀ alkyl PEG acrylates, C₁₀₋₃₀ alkyl PEG methacrylates or C₁₀₋₃₀ alkyl PEG itaconates, for example, are used as the monomer (A2). Preferred monomers (A2) are selected from C₁₀₋₃₀ alkyl acrylates, C₁₀₋₃₀ alkyl PEG 20-25 acrylates, C₁₀₋₃₀ alkyl PEG 20-25 methacrylates or C₁₀₋₃₀ alkyl PEG 20-25 itaconates. Particularly preferred monomers (A2) are selected from the group of C₁₀₋₃₀ alkyl acrylates, steareth-20 methacrylates, beheneth-25 methacrylates, steareth-20 itaconates, ceteth-20 itaconates, palmeth-25 acrylates or C₁₀₋₃₀ alkyl PEG-20 itaconates.

In summary, copolymers a) are preferred which are formed from

-   -   at least one monomer (A1) from the group of acrylic acid,         methacrylic acid, C₁-C₆ alkyl acrylic acid esters, C₁-C₆ alkyl         methacrylic acid esters,     -   at least one monomer (A2) from the group of C₁₀₋₃₀ alkyl         acrylates, C₁₀₋₃₀ alkyl PEG acrylates, C₁₀₋₃₀ alkyl PEG         methacrylates or C₁₀₋₃₀ alkyl PEG itaconates.

Copolymers a) which are formed from

-   -   at least one monomer (A1) from the group of acrylic acid,         methacrylic acid, C₁-C₆ alkyl acrylic acid esters, C₁-C₆ alkyl         methacrylic acid esters,     -   at least one monomer (A2) from the group of C₁₀₋₃₀ alkyl         acrylates, steareth-20 methacrylates, beheneth-25 methacrylates,         steareth-20 itaconates, ceteth-20 itaconates, palmeth-25         acrylates or C₁₀₋₃₀ alkyl PEG-20 itaconates are particularly         preferred.

Further preferred hydrophobically modified (meth)acrylic acid copolymers a) are formed from at least one monomer (A3) from the group of unsaturated amine-group-containing monomers in addition to the aforementioned monomers (A1) and (A2).

Monomers from the group of acrylamide, methacrylamide, mono-(C₁-C₄) alkylamino (C₁-C₄) alkyl acrylate, di-(C₁-C₄) alkylamino (C₁-C₄) alkyl acrylate, mono-(C₁-C₄) alkylamino (C₁-C₄) alkyl methacrylate, di-(C₁-C₄) alkylamino (C₁-C₄) alkyl methacrylate are preferably used as the monomer (A3).

Examples of preferred monomers (A2) are 2-(N,N-dimethylamino)ethyl acrylate, 2-(N,N-dimethylamino)ethyl methacrylates, 2-(N,N-diethylamino)ethyl acrylates, 2-(N,N-diethylamino)ethyl methacrylates, 3-(N,N-dimethylamino)propyl acrylate, 3-(N,N-dimethylamino)propyl methacrylate, 2-(N′,N-dimethylamino)neopentyl acrylate, N′-(3-N,N-dimethylamino)propyl acrylamide, N′-(3-N,N-dimethylamino)propyl methacrylamide.

Copolymers A are preferred which are formed from

-   -   at least one monomer (A1) from the group of acrylic acid,         methacrylic acid, C₁-C₆ alkyl acrylic acid esters, C₁-C₆ alkyl         methacrylic acid esters,     -   at least one monomer (A2) from the group of C₁₀₋₃₀ alkyl PEG 20         itaconates,     -   at least one monomer (A3) from the group of acrylamide,         methacrylamide, mono-(C₁-C₄) alkylamino (C₁-C₄) alkyl acrylate,         di-(C₁-C₄) alkylamino (C₁-C₄) alkyl acrylate, mono-(C₁-C₄)         alkylamino (C₁-C₄) alkyl methacrylate, di-(C₁-C₄) alkylamino         (C₁-C₄) alkyl methacrylate.

Copolymers a) which are particularly preferably used are crosslinked. Crosslinking improves the tactile properties of the agents used according to the invention. In addition, the hair-fixing effect of these agents, in particular when used in small amounts, is improved.

In summary, cosmetic compositions which are preferably used according to the invention are characterized in that the copolymer a) is selected from the group of compounds having the INCI names Acrylates/C₁₀₋₃₀ Alkyl Acrylate Crosspolymer, Acrylates/Steareth-20 Methacrylate Crosspolymer, Acrylates/Steareth-20 Methacrylate Copolymer, Acrylates/Beheneth-25 Methacrylate Copolymer, Acrylates/Steareth-20 Itaconate Copolymer, Acrylates/Ceteth-20 Itaconate Copolymer, Acrylates/Palmeth-25 Acrylate Copolymer, Acrylates/Aminoacrylates/C₁₀₋₃₀ Alkyl PEG-20 Itaconate Copolymer Corresponding polymers are available for example under the trade names Ultrez® 21, Pemulen® TR1, Aculyn® 22, Aculyn® 28, Aculyn® 88, Structure® 2001, Structure® 3001, Synthalen® W2000 and Structure® Plus. The copolymer a) is particularly preferably selected from the group of compounds having the INCI name Acrylates/C₁₀₋₃₀ Alkyl Acrylate Crosspolymer.

As the second essential constituent the cosmetic compositions used according to the invention contain at least one hydrophobically modified polysaccharide b). The proportion by weight of the polysaccharide b) in the total weight of the cosmetic composition is preferably 0.1 to 8.0 wt. %, particularly preferably 0.5 to 6.0 wt. % and in particular 1.0 to 4.0 wt. %. Preferred polysaccharides b) do not have a thickening effect.

Preferred hydrophobically modified polysaccharides have saturated or unsaturated alkyl residues and/or saturated or unsaturated arylalkyl residues with six to thirty carbon atoms. Particularly preferred hydrophobically modified polysaccharides are characterized by saturated or unsaturated C₆₋₃₀ alkyl residues, preferably by saturated or unsaturated C₈₋₁₈ alkyl residues, in particular by unsaturated C₈₋₁₈ alkyl residues. Corresponding hydrophobically modified polysaccharides are obtainable for example by etherification or esterification of the hydroxyl groups of polysaccharides. Starch ethers or starch esters are formed in this way, for example.

In a first preferred embodiment the polysaccharide b) is selected from the group of starch ethers. Starch ethers by way of example are obtained by the etherification of starch with tetramethylol acetylenediurea.

It is particularly preferable, however, for the polysaccharide b) to be selected from the group of starch esters. The group of starch esters comprises in particular also the sodium and/or aluminum salts of low-substituted semi-esters of starch, for example sodium starch octenylsuccinates or aluminum starch octenylsuccinates, which are obtainable for example by reacting starch with octenylsuccinic anhydride. Cosmetic compositions which are particularly preferably used are characterized in that the polysaccharide b) is selected from the group of starch octenylsuccinates, in particular from the compounds having the INCI name Sodium Starch Octenylsuccinate, but preferably from the group having the INCI name Aluminum Starch Octenylsuccinate.

The starch esters have proved to be superior to the starch ethers in terms of their cosmetic and tactile properties.

For the use according to the invention it has proved advantageous to maintain certain weight ratios between the copolymer a) and the polysaccharide b). It is therefore preferable according to the invention for the weight ratio of the copolymer a) to the polysaccharide b) to be 2:1 to 1:30, preferably 1:1 to 1:20 and in particular 1:2 to 1:10.

In addition to the copolymers a) and polysaccharides b) described above, the cosmetic compositions used according to the invention can contain further active agents, auxiliary substances and care substances.

A first group of active agents that are preferably used are waxes. Preferred waxes have a melting point in the range from 40° C. to 90° C., particularly preferably in the range from 50° C. to 85° C. and in particular in the range from 50° C. to 75° C. The proportion by weight of waxes relative to the total weight of the cosmetic preparation is preferably 0.1 to 10 wt. %, particularly preferably 0.2 to 8.0 wt. % and in particular 0.5 to 5.0 wt. %.

In principle, all waxes which melt in the cited temperature range and are physiologically acceptable can be used. Particularly preferred waxes according to the invention are beeswax (cera alba), carnauba wax, candelilla wax, montan wax, microcrystalline waxes (microcrystalline paraffins) and cetyl palmitate.

The teaching according to the invention also encompasses the combined use of several waxes. Thus an addition of small amounts of carnauba wax can be used to increase the melting and dropping point of another wax and to reduce its stickiness. In addition, a range of wax blends, optionally mixed with further additives, is commercially available.

Examples of blends which are preferably used according to the invention are those available under the names “Spezialwachs 7686 OE” (a blend of cetyl palmitate, beeswax, microcrystalline wax and polyethylene, with a melting range from 73-75° C.; manufacturer: Kahl & Co), Polywax® GP 200 (a blend of stearyl alcohol and polyethylene glycol stearate with a melting point of 47-51° C.; manufacturer: Croda) and “Weichceresin® FL 400” (a vaseline/vaseline oil/wax blend with a melting point of 50-54° C.; manufacturer: Parafluid Mineralölgesellschaft).

In a special embodiment of the invention “liquid waxes”, such as jojoba oil for example, can also be used in addition to the compounds which are conventionally defined as waxes.

In summary, cosmetic compositions are preferably used in particular which, relative to their total weight, contain 0.1 to 10 wt. %, preferably 0.2 to 8.0 wt. % and in particular 0.5 to 5.0 wt. % of at least one wax, preferably at least one wax from the group of beeswax and carnauba wax. The addition of wax to the cosmetic preparations used according to the invention was able to bring about an unexpected increase in volume of the temporarily shaped keratinic fibers.

The present application also provides a cosmetic composition, containing

a) at least one hydrophobically modified (meth)acrylic acid copolymer;

b) at least one hydrophobically modified polysaccharide;

c) at least one wax.

The preferred features of cosmetic compositions according to the invention correspond with the necessary changes to the preferred features of the agents used in the context of the use according to the invention.

The group of film-forming polymers forms a further preferred constituent of cosmetic compositions used according to the invention. These film-forming polymers are not identical to the hydrophobically modified (meth)acrylic acid copolymer a) described above. The proportion by weight of the film-forming polymer in the total weight of the cosmetic composition is by preference 0.1 to 8.0 wt. %, preferably 0.5 to 6.0 wt. % and in particular 1.0 to 4.0 wt. %.

Non-ionic polymers are particularly preferably used as film-forming polymers. Suitable non-ionic polymers are for example:

-   -   vinylpyrrolidone/vinyl ester copolymers, such as are sold for         example under the trademark Luviskol® (BASF). Luviskol® VA 64         and Luviskol® VA 73, both of which are vinylpyrrolidone/vinyl         acetate copolymers, are preferred non-ionic polymers.     -   cellulose ethers, such as hydroxypropyl cellulose, hydroxyethyl         cellulose and methylhydroxypropyl cellulose, such as are sold         for example under the trademarks Culminal® and Benecel®         (AQUALON).     -   shellac.     -   polyvinylpyrrolidones, such as are sold for example under the         name Luviskol®(BASF).     -   siloxanes. These siloxanes can be both water-soluble and         water-insoluble. Both volatile and non-volatile siloxanes are         suitable, wherein compounds whose boiling point under normal         pressure is above 200° C. are understood to be non-volatile         siloxanes. Preferred siloxanes are polydialkyl siloxanes, such         as for example polydimethyl siloxane, polyalkylaryl siloxanes,         such as for example polyphenylmethyl siloxane, ethoxylated         polydialkyl siloxanes as well as polydialkyl siloxanes         containing amine and/or hydroxyl groups.     -   glycoside-substituted silicones.

Polyvinylpyrrolidones (INCI name: PVP) are preferred in particular according to the invention.

Protein hydrolysates and/or derivatives thereof can be used as the care substance. Protein hydrolysates are mixtures of products which are obtained by acidically, basically or enzymatically catalyzed breakdown of proteins. According to the invention the term protein hydrolysates is also understood to include total hydrolysates and individual amino acids and derivatives thereof as well as mixtures of different amino acids. The molecular weight of the protein hydrolysates for use according to the invention is between 75, the molecular weight for glycine, and 200,000; the molecular weight is preferably 75 to 50,000 and particularly preferably 75 to 20,000 daltons.

A further group of care substances are the vitamins, provitamins, vitamin precursors and/or derivatives thereof. Those vitamins, provitamins and vitamin precursors that are conventionally assigned to groups A, B, C, E, F and H are preferred according to the invention.

Further care substances are glycerol, propylene glycol, panthenol and sorbitol.

Plant extracts and also mono- or oligosaccharides and/or lipids can be used as the care substance.

Oil bodies form a further group of care substances. The natural and synthetic cosmetic oil bodies include for example vegetable oils, liquid paraffin oils, isoparaffin oils and synthetic hydrocarbons along with di-n-alkyl ethers having in total between 12 and 36 C atoms, in particular 12 to 24 C atoms. Oil bodies from the group of silicone oils are moreover preferred. The group of silicone oils includes in particular dimethicones, which also include cyclomethicones, amino-functional silicones and dimethiconols. The dimethicones can be both linear and branched and also cyclic or cyclic and branched. Suitable silicone oils or silicone gums are in particular dialkyl and alkylaryl siloxanes, such as for example dimethyl polysiloxane and methyl phenyl polysiloxane, and the alkoxylated, quaternized or also anionic derivatives thereof. Cyclic and linear polydialkyl siloxanes, the alkoxylated and/or aminated derivatives thereof, dihydroxypolydimethyl siloxanes and polyphenyl alkyl siloxanes are preferred.

Ester oils, in other words esters of C₆-C₃₀ fatty acids with C₂-C₃₀ fatty alcohols, preferably monoesters of fatty acids with alcohols having 2 to 24 C atoms, such as for example isopropyl myristate (Rilanit® IPM), isononanoic acid C₁₆₋₁₈ alkyl ester (Cetiol® SN), 2-ethylhexyl palmitate (Cegesoft® 24), stearic acid 2-ethylhexyl ester (Cetiol® 868), cetyl oleate, glycerol tricaprylate, coconut fatty alcohol caprinate/caprylate (Cetiol® LC), n-butyl stearate, oleyl erucate (Cetiol® J 600), isopropyl palmitate (Rilanit® IPP), oleyl oleate (Cetiol®), lauric acid hexyl ester (Cetiol® A), di-n-butyl adipate (Cetiol® B), myristyl myristate (Cetiol® MM), cetearyl isononanoate (Cetiol® SN), oleic acid decyl ester (Cetiol® V), are further preferred caring oil bodies.

Furthermore, dicarboxylic acid esters, symmetrical, asymmetrical or cyclic esters of carbonic acid with fatty alcohols, tri-fatty acid esters of saturated and/or unsaturated linear and/or branched fatty acids with glycerol or fatty acid partial glycerides, which are understood to be monoglycerides, diglycerides and technical mixtures thereof, are suitable as care substances.

The water content of cosmetic compositions that are preferably used is 30 to 80 wt. %, preferably 40 to 70 wt. % and in particular 45 to 65 wt. %.

The composition of a number of cosmetic agents that are used can be taken from the tables below (amounts in wt. % relative to the total weight of the cosmetic agent unless otherwise specified).

Formula 1 Formula 2 Formula 3 Formula 4 Formula 5 Hydrophobically 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 modified (meth)acrylic acid copolymer Hydrophobically 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 modified polysaccharide Misc to 100 to 100 to 100 to 100 to 100 Formula Formula 6 Formula 7 Formula 8 Formula 9 10 Hydrophobically 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 modified (meth)acrylic acid copolymer Hydrophobically 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 modified polysaccharide Water 30 to 80 40 to 70 45 to 65 62 33 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 11 12 13 14 15 Acrylates/C10-30 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Alkyl Acrylate Crosspolymer Hydrophobically 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 modified polysaccharide Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 16 17 18 19 20 Acrylates/Steareth-20 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Methacrylate Crosspolymer Hydrophobically 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 modified polysaccharide Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 21 22 23 24 25 Acrylates/Steareth-20 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Methacrylate Copolymer Hydrophobically 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 modified polysaccharide Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 26 27 28 29 30 Acrylates/Beheneth-25 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Methacrylate Copolymer Hydrophobically 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 modified polysaccharide Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 31 32 33 34 35 Acrylates/Steareth-20 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Itaconate Copolymer Hydrophobically 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 modified polysaccharide Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 36 37 38 39 40 Acrylates/Ceteth-20 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Itaconate Copolymer Hydrophobically 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 modified polysaccharide Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 41 42 43 44 45 Acrylates/Palmeth-25 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Acrylate Copolymer Hydrophobically 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 modified polysaccharide Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 46 47 48 49 50 Acrylates/Aminoacrylates/ 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 C₁₀₋₃₀ Alkyl PEG-20 Itaconate Copolymer Hydrophobically 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 modified polysaccharide Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 51 52 53 54 55 Hydrophobically 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 modified (meth)acrylic acid copolymer Aluminum Starch 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 Octenylsuccinate Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 56 57 58 59 60 Hydrophobically 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 modified (meth)acrylic acid copolymer Aluminum Starch 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 Octenylsuccinate Water 30 to 80 40 to 70 45 to 65 62 33 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 61 62 63 64 65 Acrylates/C10-30 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Alkyl Acrylate Crosspolymer Hydrophobically 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 modified polysaccharide Wax 0.1 to 10  0.2 to 8.0 0.5 to 5.0 3.0 8.7 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 66 67 68 69 70 Hydrophobically 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 modified (meth)acrylic acid copolymer Aluminum Starch 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 Octenylsuccinate Wax 0.1 to 10  0.2 to 8.0 0.5 to 5.0 3.0 8.7 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 71 72 73 74 75 Acrylates/C10-30 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Alkyl Acrylate Crosspolymer Aluminum Starch 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 Octenylsuccinate Wax 0.1 to 10  0.2 to 8.0 0.5 to 5.0 3.0 8.7 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 76 77 78 79 80 Acrylates/C10-30 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Alkyl Acrylate Crosspolymer Hydrophobically 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 modified polysaccharide Beeswax 0.1 to 10  0.2 to 8.0 0.5 to 5.0 3.0 8.7 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 81 82 83 84 85 Hydrophobically 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 modified (meth)acrylic acid copolymer Aluminum Starch 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 Octenylsuccinate Beeswax 0.1 to 10  0.2 to 8.0 0.5 to 5.0 3.0 8.7 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 86 87 88 89 90 Acrylates/C10-30 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Alkyl Acrylate Crosspolymer Aluminum Starch 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 Octenylsuccinate Beeswax 0.1 to 10  0.2 to 8.0 0.5 to 5.0 3.0 8.7 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 91 92 93 94 95 Acrylates/C10-30 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Alkyl Acrylate Crosspolymer Hydrophobically 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 modified polysaccharide Film-forming 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 1.2 3.8 polymer* Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 96 97 98 99 100 Hydrophobically 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 modified (meth)acrylic acid copolymer Aluminum Starch 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 Octenylsuccinate Film-forming polymer* 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 1.2 3.8 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 101 102 103 104 105 Acrylates/C10-30 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Alkyl Acrylate Crosspolymer Aluminum Starch 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 Octenylsuccinate Film-forming polymer* 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 1.2 3.8 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 106 107 108 109 110 Acrylates/C10-30 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Alkyl Acrylate Crosspolymer Hydrophobically 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 modified polysaccharide Polyvinylpyrrolidone 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 1.2 3.8 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 111 112 113 114 115 Hydrophobically 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 modified (meth)acrylic acid copolymer Aluminum Starch 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 Octenylsuccinate Polyvinylpyrrolidone 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 1.2 3.8 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 116 117 118 119 120 Acrylates/C10-30 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Alkyl Acrylate Crosspolymer Aluminum Starch 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 Octenylsuccinate Polyvinylpyrrolidone 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 1.2 3.8 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 121 122 123 124 125 Hydrophobically 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 modified (meth)acrylic acid copolymer Hydrophobically 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 modified polysaccharide Wax 0.1 to 10  0.2 to 8.0 0.5 to 5.0 3.0 8.7 Water 30 to 80 40 to 70 45 to 65 62 33 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 126 127 128 129 130 Acrylates/C10-30 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Alkyl Acrylate Crosspolymer Hydrophobically 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 modified polysaccharide Wax 0.1 to 10  0.2 to 8.0 0.5 to 5.0 3.0 8.7 Water 30 to 80 40 to 70 45 to 65 62 33 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 131 132 133 134 135 Acrylates/C10-30 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Alkyl Acrylate Crosspolymer Aluminum Starch 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 Octenylsuccinate Wax 0.1 to 10  0.2 to 8.0 0.5 to 5.0 3.0 8.7 Water 30 to 80 40 to 70 45 to 65 62 33 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 136 137 138 139 140 Acrylates/C10-30 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Alkyl Acrylate Crosspolymer Aluminum Starch 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 Octenylsuccinate Beeswax 0.1 to 10  0.2 to 8.0 0.5 to 5.0 3.0 8.7 Water 30 to 80 40 to 70 45 to 65 62 33 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 141 142 143 144 145 Hydrophobically 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 modified (meth)acrylic acid copolymer Hydrophobically 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 modified polysaccharide Film-forming polymer* 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 1.2 3.8 Water 30 to 80 40 to 70 45 to 65 62 33 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 146 147 148 149 150 Acrylates/C10-30 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Alkyl Acrylate Crosspolymer Hydrophobically 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 modified polysaccharide Film-forming polymer* 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 1.2 3.8 Water 30 to 80 40 to 70 45 to 65 62 33 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 151 152 153 154 155 Acrylates/C10-30 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Alkyl Acrylate Crosspolymer Aluminum Starch 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 Octenylsuccinate Film-forming polymer* 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 1.2 3.8 Water 30 to 80 40 to 70 45 to 65 62 33 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 156 157 158 159 160 Acrylates/C10-30 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Alkyl Acrylate Crosspolymer Aluminum Starch 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 Octenylsuccinate Polyvinylpyrrolidone 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 1.2 3.8 Water 30 to 80 40 to 70 45 to 65 62 33 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 161 162 163 164 165 Hydrophobically 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 modified (meth)acrylic acid copolymer Hydrophobically 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 modified polysaccharide Wax 0.1 to 10  0.2 to 8.0 0.5 to 5.0 3.0 8.7 Film-forming polymer* 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 1.2 3.8 Water 30 to 80 40 to 70 45 to 65 62 33 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 161 162 163 164 165 Acrylates/C10-30 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Alkyl Acrylate Crosspolymer Hydrophobically 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 modified polysaccharide Wax 0.1 to 10  0.2 to 8.0 0.5 to 5.0 3.0 8.7 Film-forming polymer* 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 1.2 3.8 Water 30 to 80 40 to 70 45 to 65 62 33 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 166 167 168 169 170 Acrylates/C10-30 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Alkyl Acrylate Crosspolymer Aluminum Starch 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 Octenylsuccinate Wax 0.1 to 10  0.2 to 8.0 0.5 to 5.0 3.0 8.7 Film-forming polymer* 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 1.2 3.8 Water 30 to 80 40 to 70 45 to 65 62 33 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 171 172 173 174 175 Acrylates/C10-30 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Alkyl Acrylate Crosspolymer Aluminum Starch 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 Octenylsuccinate Beeswax 0.1 to 10  0.2 to 8.0 0.5 to 5.0 3.0 8.7 Film-forming polymer* 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 1.2 3.8 Water 30 to 80 40 to 70 45 to 65 62 33 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 176 177 178 179 180 Acrylates/C10-30 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Alkyl Acrylate Crosspolymer Aluminum Starch 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 Octenylsuccinate Wax 0.1 to 10  0.2 to 8.0 0.5 to 5.0 3.0 8.7 Polyvinylpyrrolidone 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 1.2 3.8 Water 30 to 80 40 to 70 45 to 65 62 33 Misc to 100 to 100 to 100 to 100 to 100 Formula Formula Formula Formula Formula 181 182 183 184 185 Acrylates/C10-30 0.05 to 5.0  0.1 to 4.0 0.2 to 2.0 0.6 0.3 Alkyl Acrylate Crosspolymer Aluminum Starch 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 2.7 1.2 Octenylsuccinate Beeswax 0.1 to 10  0.2 to 8.0 0.5 to 5.0 3.0 8.7 Polyvinylpyrrolidone 0.1 to 8.0 0.5 to 6.0 1.0 to 4.0 1.2 3.8 Water 30 to 80 40 to 70 45 to 65 62 33 Misc to 100 to 100 to 100 to 100 to 100 *not a hydrophobically modified (meth)acrylic acid copolymer

While at least one exemplary embodiment has been presented in the foregoing detailed description of the invention, it should be appreciated that a vast number of variations exist. It should also be appreciated that the exemplary embodiment or exemplary embodiments are only examples, and are not intended to limit the scope, applicability, or configuration of the invention in any way. Rather, the foregoing detailed description will provide those skilled in the art with a convenient road map for implementing an exemplary embodiment of the invention, it being understood that various changes may be made in the function and arrangement of elements described in an exemplary embodiment without departing from the scope of the invention as set forth in the appended claims and their legal equivalents. 

What is claimed is:
 1. A method for temporary shaping of keratin-containing fibers, comprising: applying to the keratin-containing fibers a cosmetic composition comprising a) at least one hydrophobically modified (meth)acrylic acid copolymer; b) at least one hydrophobically modified polysaccharide; and c) at least one wax; wherein at least one wax is selected from the group consisting of beeswax and carnauba wax; wherein the wax is present in an amount 0.1 wt % to 10 wt % based on the total weight of the cosmetic composition; and wherein the hydrophobically modified (meth)acrylic copolymer is present in an amount of 0.05 wt % to 5.0 wt % based on the total weight of the cosmetic composition.
 2. The method of claim 1, wherein the hydrophobically modified (meth)acrylic acid copolymer is crosslinked.
 3. The method of claim 1, wherein the hydrophobically modified (meth)acrylic acid copolymer is a compound having the INCI name acrylates/C10-30 alkyl acrylate crosspolymer.
 4. The method of claim 1, wherein the hydrophobically modified (meth)acrylic copolymer is present in an amount of 0.1 wt % to 4.0 wt % based on the total weight of the cosmetic composition.
 5. The method of claim 1, wherein the hydrophobically modified (meth)acrylic copolymer is present in an amount of 0.2 wt % to 2.0 wt % based on the total weight of the cosmetic composition.
 6. The method of claim 1, wherein the at least one hydrophobically modified polysaccharide includes a starch ester.
 7. The method of claim 1, wherein the hydrophobically modified polysaccharide is a starch octenylsuccinates.
 8. The method of claim 7, wherein the starch octenylsuccinate is aluminum starch octenylsuccinate.
 9. The method of claim 1, wherein the hydrophobically modified polysaccharide is present in an amount of 0.1 wt % to 8.0 wt % based on the total weight of the cosmetic composition.
 10. The method of claim 1, wherein the hydrophobically modified polysaccharide is present in an amount of 0.5 wt % to 6.0 wt % based on the total weight of the cosmetic composition.
 11. The method of claim 1, wherein the hydrophobically modified polysaccharide is present in an amount of 1.0 wt % to 4.0 wt % based on the total weight of the cosmetic composition.
 12. The method according to claim 1, wherein the wax is present in an amount 0.2 wt % to 8.0 wt % based on the total weight of the cosmetic composition.
 13. The method according to claim 1, wherein the cosmetic composition further comprises, based on the total weight of the cosmetic composition, 0.1 wt % to 8.0 wt % of at least one film-forming polymer that is different from the hydrophobically modified (meth)acrylic acid copolymer.
 14. The method according to claim 13, wherein the at least one film-forming polymer that is different from the hydrophobically modified (meth)acrylic acid copolymer is a polyvinylpyrrolidone.
 15. The method according to claim 13, wherein the at least one film-forming polymer that is different from the hydrophobically modified (meth)acrylic acid copolymer is present in an amount 0.5 to 6.0 wt % based on the total weight of the cosmetic composition. 